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Polystyrene vs. Polyester: Know the Difference

Shumaila Saeed
By Shumaila Saeed || Updated on December 25, 2023
Polystyrene is a synthetic aromatic polymer made from styrene monomers, primarily used in rigid products and foam insulation, whereas Polyester is a category of polymers made from ester functional groups, widely used in fabrics and textiles.
Polystyrene vs. Polyester

Key Differences

Polystyrene is a long chain hydrocarbon with alternating carbon and hydrogen atoms, derived from styrene monomers. It is a thermoplastic polymer, meaning it can be melted and remolded. In contrast, Polyester is a polymer composed of ester functional groups within its main chain, typically created from a reaction between an acid and an alcohol. Polyester's structure gives it different properties, like resistance to wrinkling and improved durability.
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Polystyrene is commonly found in disposable cutlery, CD cases, and insulation materials due to its lightweight and insulating properties. Its foam form, known as Styrofoam, is used in packaging and insulation. Conversely, Polyester is predominantly used in the textile industry for making clothing, home furnishings like curtains and bed sheets, and industrial applications such as conveyor belts and hoses, due to its strength and resistance to chemicals and wrinkles.
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Polystyrene is rigid and brittle in its solid form, with a clear, glassy appearance. It has poor resistance to UV light and can degrade, discolor, or become brittle over time. Polyester, on the other hand, is known for its high tensile strength, durability, and resistance to many chemicals. It can also retain its shape and resists shrinking and stretching.
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Polystyrene poses significant environmental concerns, as it is not easily biodegradable and can persist in the environment for centuries. Recycling polystyrene is challenging and not widely practiced. Polyester, while also a synthetic polymer, is more recyclable, and there is growing interest in developing sustainable and biodegradable forms of polyester.
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The production of Polystyrene is a process of polymerizing styrene, which is derived from petroleum, a non-renewable resource. This makes its production more dependent on the oil industry. Polyester's production, involving esterification or transesterification, can use both petrochemicals and naturally derived materials like corn. Polyester's versatility in applications makes it a very economically significant material.
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Comparison Chart

Base Monomer

Styrene
Ester (from acid and alcohol)
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Typical Uses

Packaging, Insulation, Disposable Cutlery
Clothing, Textiles, Industrial Applications
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Physical Properties

Brittle, Rigid, Clear
Strong, Durable, Resistant to Wrinkling
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Environmental Impact

Low Biodegradability, Difficult to Recycle
More Recyclable, Efforts for Sustainability
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Dependence on Oil

High (Derived from Petroleum)
Varies (Can be Petrochemical or Natural)
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Polystyrene and Polyester Definitions

Polystyrene

Commonly used for single-use items like cutlery and plates.
Polystyrene plates are often used in picnics for convenience.
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Polyester

Common in curtains, bed sheets, and upholstery.
The polyester curtains are easy to maintain and look great.
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Polystyrene

Used in model making and crafting.
The model airplane is crafted from polystyrene blocks.
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Polyester

A synthetic fabric widely used in clothing.
Her dress is made of polyester, which resists wrinkles well.
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Polystyrene

Used in building construction for thermal insulation.
We installed polystyrene sheets for better insulation in our house.
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Polyester

Used in various industrial applications like conveyor belts.
The factory uses polyester conveyor belts for their durability.
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Polystyrene

A synthetic polymer made from styrene monomers.
The coffee cup is made of polystyrene, keeping the drink warm.
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Polyester

Often blended with natural fibers for enhanced properties.
The sweater is a blend of wool and polyester, making it warm and durable.
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Polystyrene

A lightweight, protective packaging material.
The delicate glassware was secured in polystyrene for safe shipping.
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Polyester

Any of numerous synthetic polymers produced chiefly by reaction of dicarboxylic acids with dihydric alcohols and used primarily as light, strong, weather-resistant resins in boat hulls, textile fibers, adhesives, and molded parts.
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Polystyrene

A rigid clear thermoplastic polymer of styrene that can be molded into objects or made into a foam that is used as thermal insulation.
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Polyester

A wrinkle-resistant fabric of fibers made from any of these resins.
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Polystyrene

(organic chemistry) A vinylic polymer of styrene, CH2CHphenyl.
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Polyester

Any polymer whose monomers are linked together by ester bonds
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Polystyrene

(organic chemistry) An alkane chain of benzene molecules, RCH2CHphenylR.
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Polyester

A material or fabric made from polyester polymer
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Polystyrene

A polymer of styrene; a rigid transparent thermoplastic;
Expanded polystyrene looks like a rigid white foam and is used as packing or insulation
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Polyester

Of, or consisting of polyesters
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Polyester

Any of numerous synthetic resins; they are light and strong and weather resistant
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Polyester

A complex ester used for making fibers or resins or plastics or as a plasticizer
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Polyester

Any of a large class of synthetic fabrics
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Polyester

Regarded for its recyclability in textile recycling.
The recycled polyester jacket is both eco-friendly and stylish.
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Repeatedly Asked Queries

Can polyester be recycled?

Yes, polyester can be recycled, and there is growing interest in sustainable polyester.
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Is polystyrene biodegradable?

No, polystyrene is not biodegradable and can persist in the environment for a long time.
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What are common uses of polystyrene?

Polystyrene is used in packaging, insulation, and disposable cutlery.
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How is polystyrene made?

Polystyrene is made by polymerizing styrene, a derivative of petroleum.
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Can polystyrene be recycled?

While it's technically recyclable, the process is complex and not widely practiced.
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Is polyester a good fabric for outdoor use?

Yes, polyester is durable, resistant to many chemicals, and ideal for outdoor use.
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Is polystyrene used in clothing?

No, polystyrene is not typically used in clothing due to its rigid nature.
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What makes polyester popular in the textile industry?

Polyester's resistance to wrinkles, durability, and versatility make it popular in textiles.
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Is polystyrene harmful to the environment?

Yes, due to its low biodegradability and challenges in recycling, polystyrene can be harmful.
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What environmental concerns are associated with polyester?

The production of polyester, especially from petrochemicals, raises concerns about resource use and pollution.
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How does UV light affect polystyrene?

UV light can degrade polystyrene, making it brittle and discolored.
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Are there biodegradable forms of polyester?

Efforts are being made to develop sustainable and biodegradable forms of polyester.
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Is polyester resistant to heat?

Polyester has good heat resistance but can be affected at high temperatures.
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Is recycled polyester as good as virgin polyester?

Recycled polyester can have similar qualities to virgin polyester, with the added benefit of being more sustainable.
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Can polyester be used in packaging?

While not common, polyester can be used in some packaging applications, especially where durability is needed.
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Are polyester fibers breathable?

Polyester is less breathable than natural fibers but modern weaving techniques have improved its breathability.
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Are there health concerns with wearing polyester?

Generally, polyester is safe to wear, but some may experience irritation or allergic reactions.
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Is polystyrene good for sound insulation?

Yes, polystyrene foam is often used for sound insulation due to its properties.
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What is Styrofoam?

Styrofoam is a trademarked form of expanded polystyrene foam, used for insulation and packaging.
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What is the main difference in the production of polystyrene and polyester?

Polystyrene is derived from styrene (petroleum product), while polyester is made from ester groups, which can be petrochemical or natural.
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About Author
Shumaila Saeed
Written by
Shumaila Saeed
Shumaila Saeed, an expert content creator with 6 years of experience, specializes in distilling complex topics into easily digestible comparisons, shining a light on the nuances that both inform and educate readers with clarity and accuracy.

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